Martensitic transformation induced planar deformation of AlN nanoprecipitates in high nitrogen stainless steels

Abstract

Boosting the applications of high nitrogen steels requires delicate control of detrimental brittle AlN precipitates which often initiate cracking and thus degrade overall mechanical performance. Here we report that stacking faults in nano-sized AlN precipitates can be activated by martensitic transformation during quenching in a high nitrogen martensitic stainless bearing steel. Atomic-scale structure and strain analyses illuminate that the planar deformation mode, which is rarely seen in inorganic AlN ceramic precipitates, is stimulated by the martensitic transformation of the steel matrix to accommodate the transformation stresses and strains at the precipitate/matrix interfaces. The critical resolved shear stresses derived from the density functional theory study are consistent with the stress arising from the martensitic transformation obtained from the phenomenological theory of martensitic crystallography combined with phase field modeling, further validating the martensitic transformation induced plastic deformation in AlN nanoprecipitates. Our finding paves a new way to mitigate the harmful effect of AlN precipitates in high nitrogen steels and enables the production of high-quality high nitrogen steels with an upper limit of Al content raised to the normal steelmaking level, which offers new guidelines for effectively reducing the production costs of high nitrogen steels.