Mars Exploration Rovers: chemical composition by the APXS

Abstract

The Alpha Particle X-Ray Spectrometers (APXSs) on board the Mars Exploration Rovers (MERs) determine the elemental compositions of Martian samples. Improvements to the version of the instrument flown on the Mars Pathfinder (MPF) mission allow, for the first time, in situ detection and quantification of trace elements such as nickel, zinc, and bromine. The APXS measurements are performed by placing the sensor head against or immediately above the sample surface. A wealth of compositional diversity has been discovered at the two MER landing sites. At Gusev crater, fresh rock surfaces in the plains resemble primitive basalts, while rocks in the Columbia Hills are significantly weathered and enriched in mobile elements such as phosphorus, sulfur, chlorine, and bromine. Sandstones cemented by sulfates as well as evidence for clay formation have also been found in the Columbia Hills. At Meridiani Planum, the layered sedimentary rocks were found to consist primarily of sulfates mixed with siliciclastic debris. Iron-rich spherules and their fragments, confirmed to be hematitic by the Mössbauer spectrometer (MB), are found armoring the soil bedforms as well as embedded in the outcrop rocks. A variety of unusual objects, including an iron-nickel meteorite and a likely ejecta fragment similar to a Martian meteorite, have also been discovered. The elemental compositions of soils analyzed at both sites are remarkably similar, indicative of global-scale homogenization or the similarity of the soil precursors.