Marine oil spill remediation by Candelilla wax modified coal fly ash cenospheres

Abstract

Biodegradable candelilla wax (CW) was creatively used for hydrophobic modification of coal fly ash cenospheres (FACs), a waste product from thermal power plants, and a new spherical hollow particulate adsorbent with fast oil adsorption rate and easy agglomeration was prepared. CW was confirmed to physically coat FACs and the optimum mass of wax added to 3 g of FACs was 0.05 g. From a series of batch scale experiments, CW-FACs were found to adsorb oil, reaching adsorption efficiency of 80.6% within 10 s, and aggregate into floating clumps which were easily removed from the water's surface. The oil adsorption efficiency was highly dependent on hydrophobicity of the used adsorbent, the adsorption of Venezuela oil onto CW-FACs was found to be a homogenous monolayer, and the capacity and intensity of the adsorption decreased as temperature increased from 10 to 40 °C. The Langmuir isotherm model was the best fit, with the maximum adsorption capacity achieved at 649.38 mg/g. CW-FACs were also found to be highly stable in concentrated acid, alkaline and salt solutions, as well as for spills of different oil products. Furthermore, the retention rate of the oil adsorption capacity of the CW-FACs after 6 cycles of adsorption-extraction was as high as 93.2%. Therefore, CW-FACs can be widely used, easily recycled, and reused for marine oil spill remediation, which is also a good alternative disposal solution for FACs.