Manufacture of opal-matrix functional nanocomposites by catalytic dehydrogenation of isopropanol under supercritical conditions

Abstract

The products of redox reactions that occur during the manufacture of opal-matrix nanocomposites in isopropanol under supercritical conditions are studied. Experimental data, thermodynamic calculations, and reaction yield values imply that hydrogen is formed in the catalytic dehydrogenation of isopropanol to acetone under supercritical conditions. The alcohol dehydrogenation catalysts are ultrafine d-element oxides encapsulated in the pore space of an ordered opal matrix; in a closed experimental system (an autoclave), these oxides are reduced by hydrogen to metals or to lower oxides (or the oxygen stoichiometry of higher oxides changes).