Abstract
Manganiferous quartz-mica schists (4 m in stratigraphic thickness) overlie epidote amphibolite in the Chiroro River area, Hidaka Mountains, Hokkaido. The schist layers have a considerable range of A/F ratios and bulk oxidation ratios which vary from 21.5 to 100. Manganese contents are from 4 to 30 times higher than that of the average shale with 0.09% MnO. The schists are essentially quartz-white mica-biotite-Mn garnet-tourmaline-±epidote-magnetite assemblages. A highly oxidized layer (5–8 cm thick) 95 cm above the epidote amphibolite contact is characterized by viridine-piemontite-spessartine-Mn white mica-Mn tourmaline-Ti-Mn haematite indicative of both high initial manganese content and very high fO2 conditions of recrystallization.
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