Abstract
Convergent paired electrolysis is an energy-efficient model in organic synthesis. Whereas the main obstacle is the matching properties of intermediates generated in two electrodes. Herein, we develop a manganese-catalyzed atom-transfer radical addition of terminal aryl alkenes and alkynes with sulfonyl chlorides, where manganese salt plays the role of chlorine atom-transfer catalyst as well as redox mediator. This method generates analogues of chlorosulfonylated products in high regio- and stereoselectivity, which are derivatives of pharmaceutical drug and natural products.
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