Abstract
AbstractAn aerobic oxidative stereoselective denitroalkylation of β-nitrostyrenes under mild conditions by using an alkylboronic acid as the alkyl source was achieved. This protocol accepts a broad scope of β-nitrostyrenes and alkylboronic acids, leading to the formation of C(sp3)–C(sp2) bonds. Air was employed to reoxidize the resultant Mn(II) species back to Mn(III) during the catalytic cycle.
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