Abstract
A manganese-catalyzed radical 6-endo-trig cyclization of 1-isocyano-2-(1-(trifluoromethyl) ethenyl)benzenes with arylphosphine oxides which involved a novel Mn(III)/Mn(II) catalytic circle, has been developed. The reaction afforded various 4-CF3-2-phosphinoylquinolines under mild reaction conditions without any external oxidant, ligand or additive.
Published Version
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