Abstract

ABSTRACT Nitrogen losses by ammonia (NH3) volatilization can be reduced by appropriate irrigation management or by alternative N sources, replacing urea. The objective of this study was to evaluate the efficiency of irrigation management and N source combinations in decreasing NH3 volatilization from an Argissolo Vermelho Distrófico típico cultivated for 28 years with black oat (Avena strigosa) and maize (Zea mays), under no-tillage in the region of Depressão Central, Rio Grande do Sul, Brazil. The experiment was arranged in a randomized block design with split plots with three replications, where the main plots consisted of irrigation systems: no irrigation; irrigation immediately before and irrigation immediately after fertilization. The subplots were treated with different N sources: urea, urea with urease inhibitor and slow-release fertilizer, at an N rate of 180 kg ha-1, broadcast over maize, plus a control treatment without N fertilization. Ammonia volatilization was assessed using semi-open static collectors for 1, 2, 4, 6, and 10 days after N fertilization. In general, more than 90 % of total NH3-N losses occurred until three days after N fertilization, with peaks up to 15.4 kg ha-1 d-1. The irrigation was efficient to reduce NH3 losses only when applied after N fertilization. However, reductions varied according to the N fertilizer, and were higher for urea (67 %) and slightly lower for urea with urease inhibitor (50 %) and slow-release fertilizer (40 %), compared with the mean of the treatments without irrigation and irrigation before fertilization. The use of urea with urease inhibitor instead of urea was only promising under volatilization-favorable conditions (no irrigation or irrigation before N fertilization). Compared to urea, slow-release fertilizer did not reduce ammonia volatilization in any of the rainfed or irrigated treatments.

Highlights

  • Urea is the most widely used nitrogen fertilizer for broadcasting on maize in Brazil

  • N losses by ammonia volatilization depend on the environmental conditions, i.e., they can be lower in dry soil and higher when N fertilizer is applied to moist soil (Cantarella et al, 2008), and intensified at high temperatures (Tasca et al, 2011)

  • The occurrence of three rainfall events (1, 3 and 5 days after fertilization), with a total of 25 mm certainly had a restrictive effect on NH3 losses (Fontoura and Bayer, 2010), in particular the 19 mm rain on the third day after fertilization

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Summary

Introduction

Urea is the most widely used nitrogen fertilizer for broadcasting on maize in Brazil. High N losses, mainly by ammonia (NH3) volatilization, may decrease the fertilization efficiency, limiting maize yields (Fontoura and Bayer, 2010) These losses are highly influenced by environmental conditions in the days following N application (Duarte et al, 2007; Holcomb et al, 2011). OH ions are released, raising the pH in surrounding granules, favoring N conversion to ammonia and volatilization (Bouwmeester et al, 1985) In this way, NH3 losses are usually highest in the first days after N fertilization, reaching values between 28-37 % of total losses in the first three days after fertilizer application. N losses by ammonia volatilization depend on the environmental conditions, i.e., they can be lower in dry soil and higher when N fertilizer is applied to moist soil (Cantarella et al, 2008), and intensified at high temperatures (Tasca et al, 2011)

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