Maleic anhydride grafted onto high density polyethylene with an enhanced grafting degree via monomer microencapsulation

Abstract

High-density polyethylene (HDPE) is among the flexible polymers on account of its appropriate processability and adequate mechanical properties. Grafting reactive monomers such as glycidyl methacrylate (GMA) and maleic anhydride (MAH) onto polyethylene was one of the ultimate choices to improve the physicochemical properties of HDPE. MAH is an appropriate option for grafting onto HDPE owing to its low reactivity and it relatively undergoes a direct grafting onto the polymer. The grafting of MAH on HDPE copolymerization has been conducted using monomer microencapsulation method in this study. The monomer microencapsulation samples were extracted stratified using acetone and xylen. Samples were then analyzed using titration, melt flow rate, FTIR, DSC, TGA and C-NMR. The results showed the degree of paste monomer on HDPE with a microencapsulation method was greater when compared to the usual method. We were successfully improving the grafting degree of MAH onto HDPE by using a simple blending method. The pre-microencapsulated HDPE provided an increasing in grafting degree of 1.88% (HDPE-g-MAH) over the conventional one which shows the value of 1.39% (HDPE-g-MAH).