Major geological cycles substantiated by U–Pb ages and εHfi of detrital zircon grains from the Lower Rhine Basin

Abstract

Detrital zircon grains of the Cenozoic Lower Rhine Basin were dated by the U–Pb method and simultaneously analyzed for initial Hf signatures to (1) identify distinct geodynamic events recorded in the W-European basement and cover rocks and (2) estimate the addition of juvenile crust in relation to these. Approximately 350 zircon grains extracted from 4 Miocene to Quaternary sand samples were investigated by back-scattered electron (BSE) and cathodoluminescence (CL) imaging. One third of these zircons were found to be sufficiently homogeneous for laser ablation U–Pb dating, which was performed by two individual and spatially well separated laser-spot analyses on the same grain, substantiating zircons have identical ages for the two intra-grain analyses. Approximately 40 zircons showed different ages. Our U–Pb dating results document distinct periods of primary magmatic zircon growth between 2.7 and 0.03Ga. These ages correspond to worldwide known subduction–collision cycles. The oldest terrains exposed today along the Rhine River and the Alps belong to the Variscan cycle. Therefore, all zircon grains older than ca. 0.4Ga must have been extracted from Paleozoic or Mesozoic–Cenozoic cover rocks containing detrital grains inherited from pre-Variscan basement; only the Cenozoic zircons require direct transport to the basin.From the dated homogeneous zircons 34 grains were selected for Hf isotope analysis, showing large variations in initial Hf isotope ratios (εHfi) between −10.9 and +15.2. Twelve of the 13 Precambrian grains yield positive or zero εHfi values, with a single 1025-Ma old grain having a negative value of −10.9. For the 21 zircon grains younger than 0.6Ga, a series of 9 grains yield positive or zero εHfi, whereas the remaining 12 zircons have negative values as low as −5.8. Approximately 60% of the zircon crystals reflect addition of juvenile crust having positive or zero εHfi being extracted from the mantle around the time indicated by their U–Pb ages. For some cases, juvenile crust addition may be somewhat older than indicated by the U–Pb ages because zircon growth may occur during later differentiation of rocks originally devoid of zircon. For such cases, εHfi values are necessarily less positive than that of the juvenile magma, depending on the Lu/Hf and crustal residence times of the zircon-free rock. A few εHfi values between +11.4 and +15.2 corroborate the existence of highly fractionated, Lu-enriched and Hf-depleted asthenospheric mantle in Mid-Proterozoic times. In agreement with earlier detrital zircon studies, our new data demonstrate that crustal recycling during continent collision events significantly increased in Phanerozoic times, being relatively rare during Precambrian times where intra-plate plume activity and oceanic arc attachment were dominant.