Abstract
Abstract The magnetic susceptibilities of the compounds [Cu(bbip)(RO)]X (bbip = 1,3-bis(benzimidazol-2-yl)propane; R = CH3, C2H5; X = NO3, ClO4) and related alkoxo-bridged copper(II) compounds were determined over the temperature range 80—300 K. For the dinuclear entities [Cu(OR)2Cu′]2+, the strength of the exchange couplings is discussed in terms of the in-plane and out-of-plane tilts of the C–O vector from the bisector of the Cu–O–Cu′ angle.
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