Abstract
Magnetic susceptibility data on powdered samples of the dinuclear complexes (CuCl 2 •L1) 2 and (CuCl 2 •L2) 2 (L1=2,5,8-trithia[9](2,5)thiophenophane; L2=2,5,9,12-tetrathia[13](2,5)thiophenophane) have been collected in the temperature range 5-297 K. The data have been fitted to the Friedberg magnetization expression containing a molecular field correction, and from the fit, values for intradimer exchange, interdimer exchange and g have been obtained. ESR spectra yield values for g ∥ and g ⊥ that give average g values for (CuCl 2 •L1) 2 and (CuCl 2 •L2) 2 . The experimental results are correlated with structural details of the complexes
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