Magnetite-latex nanoparticle motion during capillary uptake in thin, porous layers studied with UFI‐NMR

Abstract

The transport of nanoparticles in porous media has received growing attention in the last decades due to environmental concerns in, for example, the printing industry, filtration, and transport of pollutants. Experimental studies on the imbibition of particle dispersions in porous media with sufficiently high spatial and temporal resolution are still challenging. This study shows how Ultra-Fast Imaging (UFI) NMR is an ideal tool for studying Fe3O4-latex particles penetration with a temporal resolution of 15 ms and spatial resolution of 18 µm. In the first part, it is shown that a calibration curve between the UFI‐NMR signal intensity and the particle concentration exists. In the second part, UFI‐NMR is used to study the penetration of a particles inside a thin nylon membrane during capillary uptake, which revealed liquid-particle front splitting and an inhomogeneous buildup of the particle concentration. Both the liquid-particle front splitting and inhomogeneous build up could be verified by Scanning Electron Microscopy. Our method allows to determine particle concentration profiles during capillary uptake within thin, porous media. Therefore, the technique can be easily extended to study particle penetrations in a wide variety of systems such thin interfaces, biomaterials, films, and filter media.