Magnetically Recyclable Loofah Biochar by KMnO4 Modification for Adsorption of Cu(II) from Aqueous Solutions.

Abstract

Novel KMnO4-modified loofah biochar loaded with nano-Fe2O3 (FMLB) was successfully synthesized for Cu(II) adsorption. Nitrogen adsorption method, scanning electron microscope, X-ray photoelectron spectroscopy, Fourier transform infrared spectrometer, and other characterization measurements were used to evaluate the physical and chemical properties of FMLB and nano-Fe2O3-loaded biochar (FLB). The results show that the adsorption behavior of Cu(II) can be best fitted by the Langmuir isotherm model and the pseudo-second-order (PSO) kinetic model, indicating that the surface of FMLB was composed of homogeneous adsorption, and chemical adsorption dominated the adsorption process under optimal reaction conditions. The adsorption capacity of FMLB is improved by 42.86% compared to FLB, and it remained over 75% after four cycles. The inner-sphere complexes with manganese oxide (MnOx) and oxygen-containing functional groups, as well as electrostatic interaction, physical adsorption, and ion exchange, play important roles in Cu(II) adsorption. The saturation magnetization of FMLB was 10.41 emu/g, ensuring that it can be easily separated from aqueous solutions. Therefore, magnetically recyclable biochar modified by KMnO4 is a feasible method for Cu(II) adsorption.