Magnetically Enhanced Bicelles Delivering Switchable Anisotropy in Optical Gels

Abstract

Mesostructures responding to external triggers such as temperature, pH, or magnetic field have the potential to be used as self-acting sensors, detectors, or switches. Key features are a strong and well-defined response to the external trigger. Here, we present magnetic alignable bicelles embedded into a gelatin matrix generating magnetically switchable structures, which can reversibly be locked and unlocked by adjusting the temperature. We show that the disk-like aggregates can be orientated in magnetic fields, and such orientation can be preserved after embedding into gelatin. The resulting gel cubes show an anisotropic transfer for electromagnetic waves, i.e., a different spatial birefringence. Cycling through the melting point of gelatin sets the structure back to its isotropic state providing a read-out of the thermal history. Stacking of the bicelles induced by the gelatin promotes magnetic aligning, as an increased aggregation number in the stacks increases the magnetic orientation energy.