Abstract
We describe magnetic susceptibility and electron spin resonance measurements of solutions of lithium in the non-aqueous solvent hexamethylphosphoric triamide over the temperature range 4–270 K. The concentration of lithium was varied from 1 to 6 mol% lithium. Our results reveal the coexistence of at least two distinct, magnetically isolated species; a localised electron species being predominant at low metal concentrations and low temperatures, and a metallic, itinerant electron state becoming dominant as the lithium concentration is increased. These results point to a considerable degree of aggregation of centres in the freezing process.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Faraday Transactions 2
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
