Abstract
NaFeSO${}_{4}$F and NaCoSO${}_{4}$F crystallize in the maxwellite crystal structure and consist of one-dimensional chains of corner-sharing $M$O${}_{4}$F${}_{2}$ octahedra linked together through F atoms sitting in a trans configuration with respect to each other. Magnetic susceptibility measurements and low-temperature powder neutron diffraction indicate that both the Fe- and Co-based phases establish $G$-type antiferromagnetic ground states below 36 and 29 K, respectively. We discuss the obtained magnetic structure in the context of the local anisotropy of the two magnetic ions.
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