Abstract

Effects of Co content on the magnetic properties and microstructure of melt-spun [(Fe1−xCox)0.675Pt0.325]84B16 (x=0–0.5) and [(Fe1−yCoy)0.725Pt0.275]85B15 (y=0 and 0.3) nanocomposite ribbons have been investigated. The substitution of Co for Fe in [(Fe1−xCox)0.675Pt0.325]84B16 ribbons enhances the coercivity (Hci) from 7.5kOe for x=0to10kOe for x=0.3, due to the formation of ordered L10-(Fe,Co)Pt phase with higher anisotropy field. The effect of Co substitution for Fe in [(Fe1−yCoy)0.725Pt0.275]85B15 series ribbons is similar to that in [(Fe1−xCox)0.675Pt0.325]84B16 system. Interestingly, larger magnetization could be obtained by decreasing the boron and Pt content simultaneously. Moreover, L10-(Fe,Co)Pt phase provides [(Fe0.7Co0.3)0.725Pt0.275]85B15 ribbons sufficient high coercivity Hci=5.4kOe, resulting in a remarkable enhancement of energy product from 10.0MGOe for Co-free ribbons to 15.7MGOe for ribbons with y=0.3.

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