Abstract
Crystallographic analyses and magnetic measurements for two polymorphs, the prism form and the needle form of bis [ N-(4-chlorophenyl) salicylideneaminato] oxovanadium (IV) are carried out. The polymeric structure is observed for the needle form against the monomeric structure for the prism form. The ferromagnetic interaction is observed for the needle form, while the appreciable magnetic coupling is not detected for the prism form. The large negative spin density is found on each of the axial oxygen of these crystals. The intermolecular ferromagnetic interaction of these complexes is greatly affected by the formation of polymeric V O⋯V O⋯ structures in the solid state.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
