Abstract

Abstract We report on the magnetic properties of the complex bimetallic compound [Cr(H 2 O)(NH 3 ) 5 ][FeCl 6 ] studied by ac magnetic susceptibility and magnetization techniques in the range 1.5–30 K and 0–40 kOe. The crystal structure contains discrete [Cr(H 2 O)(NH 3 ) 5 ] 3+ and [FeCl 6 ] 3- ions, held together by ionic forces and by a network of hydrogen bonds. At temperatures below (2.32±0.01) K the compound seems to behave as a noncollinear ferrimagnet. In addition, the experimental H-T magnetic phase diagram has been derived.

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