Abstract

The magnetic susceptibilities and magnetic moments of the ammonium salt of cupferron and manganese, cobalt, nickel and copper divalent complexes are investigated. The ammonium salt of cupferron is diamagnetic while the divalent transition metal cupferron complexes exhibit paramagnetic behaviour. For manganese, cobalt and nickel cupferrates the magnetic moment is smaller than the spin-only value, which reflects the effect of the orbital angular momentum and electron delocalization. For copper cupferrate the magnetic moment is nearly equal to the spin-only value.

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