Abstract
Examples from the (R 1,R 2-DCNQI) 2X family of molecular conductors have been studied using μSR in order to provide information about the microscopic magnetic properties of the various phases. For the fully deuterated dimethyl Cu salt (d 8-DMe-Cu) there is a metalinsulator (MI) transition around 80 K and a magnetic transition around 7 K. The muon spin relaxation rate becomes enhanced in the region of the MI transition and below, reflecting the quenching of valence fluctuations and the appearance of localised spins on the Cu sites. A zero field precession signal develops below 7 K as a result of the 3D magnetic ordering of the Cu spins; the field distribution derived from the precession frequency is consistent with the proposed magnetic structure. In addition to the zero field studies, nuclear quadrupolar level crossing resonance between the muon and the imine nitrogen of the DCNQI has been used to study the temperature dependence of the electronic state of the molecular conductor.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
