Abstract
It is shown by EPR and magnetic susceptibility (χ) measurements that acetate-N-methyl-octaethylporphyrinato-Co(II) has a high-spin ground state. The complex in toluene gives EPR spectra with g= 4.4 and 2.04 and χ with μ eff= 4.4 BM and D ≈ 20 cm −1, which indicates square-pyramidal geometry around Co (II). Data for the undiluted system are analyzed in terms of a dimer model with a small exchange interaction.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
