Abstract
The magnetic properties of metal‐organic framework compounds [M2(C8H4O4)2 · C6H12N2] (M = Cu, Ni, Co) were studied in the region of 300–4 K by magnetic susceptibility and 1H magic‐angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy. The interaction between the magnetic ions M was found to be antiferromagnetic at the temperatures above 100–150 K. Lowering the temperature changes the interaction character to ferromagnetic. The exchange interaction was found between 1,4‐diazabicyclo[2,2,2]octane (dabco) molecules and magnetic ion.Magnetic properties in metal‐organic framework compound.
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