Magnetic properties and resistivity of a 2:17-type SmCo magnet doped with ZrO2 * *Project supported by the National Natural Science Foundation of China (Grant No. 51877094) and Ningbo Science and Technology Project (Grant No. 2014B11009).

Abstract

In order to counteract the demagnetization caused by eddy current loss, widespread attention has been devoted to increasing the resistivity of permanent magnets. We prepared 2:17-type SmCo magnets doped with different ZrO2 contents and investigated the influence of the ZrO2 content on the magnetic properties and resistive anisotropism. The results showed that not only was the resistivity of the magnet improved, but, in addition, the coercivity of the magnet was significantly increased. The microstructure was studied with TEM, which showed that ZrO2 doping was able to cause a decrease in the lamellar phase density and the growth of cellular structures. The increased grain boundaries and Sm2O3 phases were favorable to the improvement of resistivity. The decrease of the lamellar phases caused a narrowing of the resistive anisotropism. The additional Cu in the center of the cellular boundaries was the main reason for the enhancement of H cj. However, an excessive amount caused an increase of the Zr6(FeCo)23 phase and a deterioration of the cellular structure, thereby leading to a decrease in coercivity.