Abstract

Distorted tetrahedral symmetry (D 2d) of two crystallographically nonequivalent copper tetrahedrons is postulated on the basis of reflectance spectrum, magnetic susceptibility measurements and EPR single crystal spectra. Molecular g-values are g ∥ = 2.292(4) and g ⊥ = 2.051(4). Exchange coupling determined by computer simulation is equal to | J | = 0.0030(5) cm −1.

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