Abstract
The magnetic properties of polycrystalline samples of Mn 1−xT iP (T Ni, Mo and W for 0.00 ⩽ t ⩽ = 0.40) are studied by magnetic susceptibility and magnetization measurements. The magnetic, composition-temperature phase diagrams are given. The extension of the magnetic ordered phases [ferromagnetic (F) or helimagnetic (H c )] brings additional experimental support for the number of valence electrons as the major factor determining the “strength” of the co-operative modes in transition metal substituted MnP. Mo and W substitution (contrary to the isoelectronic substituent T Cr) increases the domain of the H c mode, whereas Ni substitution (contrary to T Fe and Co) stabilizes the F mode.
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