Abstract
We revealed a new protocol to support Pt nanoparticles on magnetic ionic liquid functionalized organosilica nanoparticle matrix. The proposed catalyst system was synthesized by sol–gel condensation method, where two silica precursors [tetraethyl orthosilicate (TEOS) and bis-silylated ionic liquid monomer] were used to carry hydrophobic magnetic nanoparticles. The Pt metal was supported on the skeleton of magnetic organosilica hybrid nanoparticles by adsorbing platinum salt (Na2PtCl4) (replaced by ion exchange method). Furthermore, sodium borohydride was used to reduce platinum salt to Pt NPs. The synthesized catalytic system was used for CO2 hydrogenation reaction under high-pressure reaction condition. An external magnetic field was used to informally recover the catalyst and further recycled for three runs (without ionic liquid medium). Task-specific ionic liquids were also manipulated as a reaction medium not only to capture the CO2 gas but also to improve the reaction in a more precise manner. Desired results were attained while using 1,3-di (N, N-dimethylaminoethyl)-2-methylimidazolium nonafluorobutanesulfonate ([DAMI][CF3CF2CF2CF2SO3]) task-specific ionic liquid and we isolated the formic acid in good TON/TOF value. We easily reused the catalytic system up to 8 runs without decreasing the performance and stability of the catalytic system.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
