Abstract
In the Heusler alloy Pd2MnSb (Z′) agreement has been found between the experimental values of magnetic hyperfine fields of 5sp shell impurities Z′ that substitute Sb and the theoretical predictions of Blandin and Campbell |2|. The decrease of the field when the 5sp shell is nearly full lends support to conduction electron polarization models based on the Daniel Friedel |4| type of theory. In view of these results, the rise of the field of 5sp impurities in iron right up to shell closure remains puzzling.
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