Magnetic Field Tuning Ionic Current Generated by Chiromagnetic Nanofilms.

Abstract

The realization of chiral magnetic effect by macroscopically manipulating quantum states of chiral matter under the magnetic field makes a future for information transmission, memory storage, magnetic cooling materials etc., while the microscopic tiny signal differences of at the interface electrons are laborious to be discerned. Here, chiromagnetic iron oxide (Fe3O4) nanofilms were successfully prepared by modulating the magnetic and electrical transition dipoles and combined with confined ion transport, enabling magnetic field-tunable ionic currents with markedly ∼7.91-fold higher for l-tartaric acid (TA)-modified Fe3O4 nanofilms than that by d-TA. The apparent amplification results from the charge redistribution at the ferromagnetic-organic interface under the influence of the chiral magnetic effect, resulting in a significant potential difference across the nanofilms that drive ion transport in the confined environment. This strategy, on the one hand, makes it possible to efficiently characterize the electronic microimbalance state in chiral substances induced by the magnetic field and, on the other hand realizes the discrimination and highly sensitive quantitative detection of chiral drug enantiomers, which give insights for the in-depth understanding of chiral magnetic effects and efficient enantiomeric recognition.