Abstract
We present direct evidence that the giant magnetocaloric effect recently discovered in the ${\mathrm{Gd}}_{5}{(\mathrm{S}\mathrm{i}}_{1.8}{\mathrm{Ge}}_{2.2})$ alloy is associated with a field-induced first-order structural transition from a ${P112}_{1}/a$ monoclinic (paramagnetic) to a Pnma orthorhombic (ferromagnetic) structure. A large volume contraction of $\ensuremath{\Delta}V/V\ensuremath{\cong}0.4%$ takes place spontaneously at the transition temperature, ${T}_{C}\ensuremath{\cong}240\mathrm{K}.$ The reported structural transition can be induced reversibly by application of an external magnetic field, producing strong magnetoelastic effects.
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