Magnetic Fe3O4 nanoparticles as easily separable catalysts for efficient catalytic transfer hydrogenation of biomass-derived furfural to furfuryl alcohol

Abstract

Magnetic Fe3O4-12 nanoparticles, an easily separable heterogeneous catalyst, exhibits high catalytic performance in the catalytic transfer hydrogenation (CTH) reaction of biomass-derived furfural (FAL) to furfuryl alcohol (FOL) with 2-propanol (2-PrOH) as the hydrogen source (90.1 % FOL yield at 160 °C for 5 h). Comparing Fe3O4 nanoparticles with different particle sizes found that the smaller the nanoparticles, the larger the BET surface area, pore volume and pore diameter, resulting in more acid-base active sites through BET, SEM, TEM, NH3-/CO2-TPD and other characterizations. Moreover, a scaled-up CTH experiment of FAL and a stepwise reaction from xylose to FOL verified that the catalytic system has great industrial application prospects. A feasible flowchart of the chemical process from xylose to FOL was designed, which can realize the regeneration of biomass resources (xylose derived from corncob), the reuse and recycling of catalysts and solvents, and minimize the amount of solvents and pollutant emissions.