Abstract

In FeTiO3, CoTiO3 and NiTiO3 the dominant magnetic exchange interactions are held to be of super-superexchange type, using two oxygens or one oxygen and one diamagnetic Ti4+ ion between the pairs of paramagnetic cations. In order to explain the antiferromagnetic ordering of manganese spins in the same layer in MnTiO3 it is suggested that the metal cations are Mn4+ and Ti2+, the interactions being of the same superexchange types as those previously suggested for Cr2O3.

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