Abstract
A model is described for the calculation of the principal magnetic susceptibilities of exchange-coupled binuclear cobaltn species. The two-centre exchange calculation is performed within a basis constructed from appropriately antisymmetrized products of the one-centre functions belonging to the 4 F + 4 P terms. The exchange parameters refer to interactions between separate one-centre orbitals, in the spirit of Anderson’s kinetic and potential exchange pathways, so bearing some resemblance to the angular overlap parameters used to describe the one-centre, ligand-field perturbation.
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