Abstract
Abstract The magnetic properties of three 1D copper(II) salts are reported. The compound Cu(14ane)Cu(N 3 ) 4 contains alternating site chains with weak FM coupling with J/k=0.635 K . Magnetization studies are reported on Cu(TIM)CuCl 4 , an alternating site, alternating FM/AFM exchange system with J FM /k=29.7 K and J AFM /k=−8.66 K . (HPy) 2 Cu 3 Cl 8 .2H 2 O contains FM chains composed of alternating Cu 2 Cl 6 2− dimers and CuCl 2 (H 2 O) 2 monomers, with intradimer coupling J 1 /k=17.35 K and dimer-monomer coupling J 2 /k=1.93 K .
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