Abstract
In order to understand magnetic behavior observed in CmO${}_{2}$ with a nonmagnetic ground state, we numerically evaluate magnetic susceptibility on the basis of a seven-orbital Anderson model with spin-orbit coupling. Naively we do not expect magnetic behavior in CmO${}_{2}$, since Cm is considered to be a tetravalent ion with six $5f$ electrons and the ground state is characterized by $J=0$, where $J$ is total angular momentum. However, there exists a magnetic excited state and the excitation energy is smaller than the value of the Land\'e interval rule due to the effect of crystalline electric-field potential. Then, we open a way to explain magnetic behavior in CmO${}_{2}$.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.