Magnetic and transport properties of Nd 1.67Sr 0.33NiO 4

Abstract

Nd 1.67Sr 0.33NiO 4 polycrystals have been prepared by modified sol–gel method and subsequent annealing. X-ray diffraction analysis, electrical resistivity, magnetic susceptibility and thermal magnetisation have been measured. Rietveld analyses show a tetragonal or pseudo-tetragonal K 2NiF 4-type structure. The resistivity measurements present a change in conduction mode close to 230 K, which corresponds to the charge ordering temperature. Below this temperature, the material adopts a variable range hopping conduction mode; and above, the conduction follows adiabatic thermal activated mode. The magnetic measurements show paramagnetic behaviour in the range of 80–300 K. Moreover, the magnetic susceptibility data show a sign of the charge ordering transition about 230 K.