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Abstract
High-resolution 25Mg NMR data are reported for a single crystal of pure forsterite (Mg2Si04) at temperatures to about 1400 °C, which allow rates of exchange of Mg cations among specific sites in the structure to be obtained. Results are consistent with estimates of hopping frequencies derived from macroscopic diffusivity data, suggesting that this approach holds potential for tracing microscopic diffusion pathways in even very refractory minerals.
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