Abstract

The separation and purification of magnesium chloride from brines, and concentration of other valuable elements from those brines are important for industrial use. Basic data are needed to design industrial processes. Therefore, the phase equilibrium of the ternary system magnesium chloride–dioxane‐water (MgCl2‐C4H8O2‐H2O) at five different temperatures (278.15K, 288.15K, 298.15K, 308.15K and 318.15K) is studied systematically by an isothermal solution saturation method. The achieved data are presented and compared to literature, if existing. The XRPD pattern of MgCl2·6H2O·C4H8O2 and MgCl2·2C4H8O2 are also obtained and presented.

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