Magmatic–hydrothermal evolution of the Anjerd Cu skarn deposit, NW Iran: Perspectives on mineral chemistry, fluid inclusions and stable isotopes

Abstract

The Anjerd Cu skarn deposit is located 40 km north of Ahar, NW Iran, which comprises three different stages of skarn–type mineralization and metasomatic alteration including (i) prograde, (ii) early retrograde and (iii) late retrograde. Prograde stage is identified by garnet as andradite–grossularite and diopsidic pyroxene crystallization, whereas retrograde stage overprinted the prograde skarn and is predominantly composed of tremolite, actinolite, quartz, epidote and chlorite. Metasomatic alteration started with generation and evolution of the mineralizing fluids in the Shayvar batholith, followed by the fluids ascending into fractures of the skarn in the metamorphic zone. Subsequently, retrograde alteration continued to the end of the skarnification process. Based on mineral chemistry studies, garnet is dominated by andradite (27–78 mol. %) and grossularite (20–67 mol. %) compositions and pyroxenes by diopside (65–98 mol. %) and hedenbergite (2–34 mol. %) compositions. Based on detailed petrography studies, three types of fluid inclusions were recognized including two–phase liquid–rich (LV), vapor–rich (VL), and three–phase (LVS) inclusions. The characteristic of the mineralizing fluids during the skarn evolution was changed significantly from early retrograde stage with (i) high temperature (up to 460 °C) and high salinity (up to 39 wt% NaCl equiv.), through late retrograde stage with (ii) moderate to high temperature (334 to 446 °C) and low salinity (0.3 to 0.8 wt% NaCl equiv.), (iii) low to moderate temperature (158 to 362 °C) and moderate salinity (1.7 to 12.3 wt% NaCl equiv.), suggesting that high–temperature and moderately saline fluids are indicative of a magmatic source within the minerals belonging to the prograde skarn, while the fluids with lower temperature and low to moderate salinity indicating a meteoric source for the retrograde skarn assemblage. The δ18O values for prograde garnet and magnetite vary from ∑0 to 8.2‰, whereas δ18O and δD values for retrograde calc–silicates in equilibrium with fluid including epidote range from 6.7 to 9.2‰ and −10.2 to −31.4 and for chlorite range from 1.9 to 2.7‰ and −37.5 to −48.1‰, respectively, pointing out that mixing of magmatic fluids with meteoric water in the retrograde alteration. Moreover, the δ34S values of pyrite and chalcopyrite (−3.6 and +4.9‰), suggesting a magmatic source for sulfur which was largely responsible for the mineralization in the Anjerd deposit.