Abstract
Back Cover: Highly isospecific polymerization of silyl-protected ω-alkenols, using a combination of [OSSO]-type bis(phenolato) dichloro zirconium(IV) complex and dMAO as the precatalyst and the activator, respectively, is established. This method represents the first example for a stereoselective polymerization of polar functional α-olefins ([mmmm] > 95%). Subsequently, the obtained terminal siloxy-substituted isotactic polymer could be readily transformed by a macromolecular desilylation/acetylation reaction sequence to afford the corresponding terminal acetyl-enriched polymer. Further details can be found in the article by Y. Saito, N. Nakata,* and A. Ishii* on page 969.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
