Machinable boron-doped diamond as a practical heating element in multi-anvil apparatuses.

Abstract

Being refractory and X-ray transparent, a boron-doped diamond (BDD) heater is considered an ideal heating element in a multi-anvil apparatus under diamond-stable pressures. However, the extremely high hardness of diamond makes it difficult to manufacture a BDD tube, which, in turn, hinders the wide application of BDD heaters in multi-anvil apparatuses. Here, I sintered a machinable BDD (MBDD) from a mixture of BDD powder and pitch (CnH2n+2) by its annealing in Ar at 1273K for 5 h. The BDD powder was bound by a small amount of graphite (<10 wt. %) during the sintering process. Tubes (such as 1.2/0.7/4.0mm in outer/inner diameter/length) can be manufactured from the MBDD block using a lathe or a computer numerical control machine. Due to the low content of graphite in MBDD, the graphite-diamond conversion has a small effect on heating performance. The MBDD heater shows a comparable performance in ultrahigh temperature generation with a high-pressure synthesized BDD heater by generating a temperature higher than 3300K and melted Al2O3 under a pressure of 15GPa. With good heating performance and excellent machinability, MBDD is a practical heating element in multi-anvil apparatuses. The achievement of stable temperature generation over 3300K by the MBDD heater enables various measurements on the physicochemical properties of melts under the Earth's mantle conditions.