Abstract

Elements in the range 39 ≤ Z ≤ 56 were excited by electrons of an energy between 3 and 15 keV. The X-rays were detected by means of an energy dispersive Si(Li) spectrometer with an ultra-thin polymer entrance window. In all cases Mζ = M5N3 was found to be the most intense M line. Thus, the relative intensity of this line is by definition 100%. For the heavier of the investigated elements some other M lines were observed: M5O3, Mγ and M2N4. Mγ was detectable for Z ≥ 47, starting with a relative intensity of about 5%, which increased rapidly with Z to approximately 10%. M5O3 was first observed for 49-In, with a relative intensity of less than 10%, which increased up to approximately 50% for 56-Ba. Also, M2N4 was observed for Z ≥ 49. The relative intensity of that line is approximately one half of that of Mγ.

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