Abstract

The M-shell satellite structure of W X-ray emission lines excited by electron bombardment is investigated by a high resolution single crystal spectrometer, and the obtained structure is further compared with calculated transition energies obtained by the Relativistic Density Functional method. The transition hole states situated in the N- and O-shells—due to Coster–Kronig transitions—correspond to the parts of the spectra situated in the close neighbourhood of the diagram transition (0.7–4.4 eV).

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