M (Co, Ni), N and S tridoped carbon nanoplates as multifunctional catalysts for rechargeable Zn-air batteries and water electrolyzers

Abstract

Exploration of multifunctional non-precious metal catalysts towards oxygen reduction reaction (ORR), oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is very important for many clean energy technologies. Here, two trifunctional catalysts based on M (Co, Ni), N and S tridoped carbon nanoplates (Co/N/S-CNPs and Ni/N/S-CNPs) are reported. Due to the relatively higher catalytic site content, graphitization degree and smaller charge-transfer resistance, the Co/N/S-CNPs catalyst shows higher activity and stability for ORR (onset potential of 0.99 V and half-wave potential of 0.87 V vs. RHE (reversible hydrogen electrode)), OER (overpotential at 10 mA cm−2 of 0.37 V) and HER than the Ni/N/S-CNPs catalyst. Furthermore, when constructed with the Co/N/S-CNPs and commercial 20 wt% Pt/C + Ir/C cathodes, respectively, Zn-air battery (ZnAB) based on the Co/N/S-CNPs cathode displays better performance, including a higher power density of 96.0 mW cm−2 and cycling stability at 5 mA cm−2. In addition, an alkaline electrolyzer assembled with the Co/N/S-CNPs catalyst as a bifunctional catalyst can reach 10 mA cm−2 at 1.65 V for overall water splitting and maintain excellent stability even after cycling for 12 h. The present work proves the potential of the Co/N/S-CNPs catalyst for many clean energy devices.