Abstract

Amidogen (NH2), a b-type asymmetric top molecule with electric dipole moment 1.82 ± 0.05 Debye, is detected in Sgr B2, in high-mass star-forming regions W31C (G10.6−0.4), W49N (G43.2−0.1), W51 (G49.5−0.4), G34.3+0.1, and in several comets. Because of two hydrogen atoms, each with nuclear spin 1/2, its rotational energy levels can be classified into ortho and para groups. We have not considered for fine structure splitting and hyper-fine structure splitting of rotational levels. For 15 rotational levels in the ground vibrational state, having energy up to 400 cm−1, for each specie, the energies of rotational levels, and Einstein A and B coefficients for radiative transitions between the levels are calculated, using accurate values of spectroscopic data. These radiative transition probabilities along with the collisional rate coefficients (obtained from a scaling law) are employed as input parameters for solving a set of statistical equilibrium equations coupled with the equations of radiative transfer for each group. Several emission lines produced by amidogen are found. For each species of NH2, we have considered some strongest emission lines along with the observed one, which may help for identification of NH2 in the interstellar medium (ISM) and in the cometary material.

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