Luminescent down-shifting natural dyes to enhance photovoltaic efficiency of multicrystalline silicon solar module

Abstract

The short wavelength photons (below 500 nm) of the solar spectrum are under-utilized in multicrystalline silicon (mc-Si) solar modules because of their high surface recombination losses. The application of luminescent down-shifting (LDS) materials is an effective way to utilize the short wavelength photons to enhance the efficiency of a mc-Si solar module. This study utilized four ‘natural’ dyes extracted from the wheat husk, rice husk, turmeric rhizomes (Curcuma longa L.), and Moringa Oleifera leaves for LDS application. These natural dyes showed absorption in the UV and blue range, and emission in the visible range which is effectively utilized by the silicon solar cell. Optimum concentrations of the natural dyes were incorporated in the front ethylene vinyl acetate (EVA) layers which were used to encapsulate bare Si cells into photovoltaic (PV) modules. The mc-Si PV modules which had the front encapsulation of EVA films containing the turmeric and moringa dyes showed relative enhancement of ~ 6.8% (±3.6) and ~ 9% (±4) respectively, in their efficiencies with respect to that of the corresponding bare silicon cells. The gains in the photovoltaic efficiency obtained with the turmeric and moringa dyes were found to be comparable to (or slightly greater than) the values reported in the literature using various Eu3+ based lanthanide complexes as LDS materials. Finally, the inclusion of natural LDS dyes in the encapsulating EVA layer would offer an economical and pro-environmental solution at high volume manufacturing to improve the utilization of short-wavelength photons.