Abstract
A series of cyclometallated 2-phenylpyridine Pt(II) complexes having N-benzoyl thiourea derivatives as ancillary ligands were prepared and characterised by elemental analysis, IR and UV–Vis spectroscopy, 1H and 13C NMR spectroscopy as well as by X-ray diffraction on single-crystal. All complexes were obtained as a single isomer with N atom of the 2-phenylpyridine ligand and S atom of the N-benzoyl thiourea derivatives coordinated in trans positions to the platinum metal as evidenced by using X-ray crystallography and NMR spectroscopy. All Pt(II) complexes show good luminescence properties at room temperature, both in dichloromethane solution and in solid state.
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