Luminescence property in Er3+/Tm3+/Ag NPs doped tellurite glass applied for broadband amplifier

Abstract

In this study, tellurite glasses co-doped with Er3+/Tm3+ were synthesized through the melt-quenching technique. Under 808 nm excitation, the spectral overlap of 1.53 µm band fluorescence generated by the transition of Er3+:4I13/2→4I15/2 and 1.47 µm band fluorescence generated by the transition of Tm3+:3H4→3F4 achieved the near-infrared (NIR) broadband flat fluorescence emission in the range of 1350–1650 nm, in which the most flat fluorescence emission was achieved when the doping amount of Er2O3 and Tm2O3 was 0.1 and 0.8 mol%, respectively, and the full width at half maximum (FWHM) reached 161 nm. Subsequently, the NIR fluorescence intensity was enhanced by introducing silver nanoparticles (Ag NPs) based on broadband flat fluorescence emission. The optimal conditions conducive to broadband fluorescence enhancement were explored by changing the heat-treated time that could affect the formation and growth of Ag NPs. When the amount of AgCl is 0.5 mol%, tellurite glass co-doped with Er3+/Tm3+ ions heat-treated at temperature 410 ℃ for 6 h has the best enhancement effect of 81 %. After transmission electron microscopy (TEM) measurement, the introduced Ag NPs’ diameter at this time is about 18 nm. Some important spectral parameters of Er3+ and Tm3+ ions, for instance the radiative transition probability together with radiative lifetime were calculated from the absorption spectra according to the Judd-Ofelt theory. Structural characteristics based on X-ray diffraction analysis and thermal stability based on differential scanning calorimeter analysis was presented. Based on the above research, the enhanced broadband and flat fluorescence in the 1350–1650 nm range is of great significance for the application of broadband optical amplifiers in modern WDM networks.